Hi welcome to the community.
This product is fairly new and few own. Give it a few days for potential other owners to chime in, for now you’re going to get educated guesses from similar products.
What @Tank said may be true that your device draws too little lower , such as when device is (nearly) fully. At a lower power level Powercore we had that issue with some phones but mostly with earbuds which drew so little power when nearly full the Powercore turned off. Powercore then added a trickle charge mode of press hold power button, blue light went green and it would not turn itself off so easily. See if a press hold of power button cures it.
If you’re wondering why the above it is because there is finite amount of stored energy in such portable power, it burns a small amount of that energy to keep the charging electronics on and if your device is nearly full and it drains little power it’s dumb to keep the power on, unless you explicitly want it kept on hence the invention of trickle charge mode.
Then possibly the opposite problem that your device is taking so much power it nearly empties the Powerhouse as it’s quite small, it cannot sustain the required Wattage and turns off the AC port. Lithium cells release lower Watts when less full so it would not be a surprise if the 100Wh capacity cannot all be given out as AC. This scenario may be diagnosed if you have an AC meter to measure Wh out.
One way to help diagnose either scenarios is a AC meter to measure output. If the first scenario the Watts would drop and then turn off. The last scenario the Watts are high then stop.
Shoot an email to support@anker.com also, they will probably know more as it’s a new product, a reply on Monday would.be best guess.