I have a powercore 10000 (model A1263) and a powercore+ 10050 (model A1310), both are old but have worked well for years. Neither will charge my controller when my ps5 is on. They will when it’s off though
Anker devices fail to charge the PS5's DualSense controller
Same I use my anker 333 cable with my PS5 pad and it works fine for me